How to Charge and Discharge Lifepo4 Battery?

By Gerald, Updated on February 5, 2024

Part 1. Structure and principle of lithium LFP battery

LiFePO4 battery structure

The components of a LiFePO4 battery include a positive electrode, negative electrode, electrolyte, diaphragm, positive and negative electrode leads, center terminal, safety valve, sealing ring, shell, etc. The positive electrode material of lithium iron phosphate batteries is generally called lithium iron phosphate, and the negative electrode material is usually carbon.
On the left is LiFePO4 with an olivine structure as the battery’s positive electrode, which is connected to the battery’s positive electrode by aluminum foil. In the middle is a polymer separator that separates the positive and negative electrodes. Lithium ions Li+ can pass through, but electrons e- cannot. On the right is the battery’s negative electrode, composed of carbon (graphite) and connected to the battery’s negative electrode by copper foil.

The structural characteristics of the LFP battery cathode material determine the low conductivity of the material itself, as well as the material’s stability and safety performance.

Principle of LiFePO4 battery

When the LFP battery is charged, lithium ions migrate from the surface of the lithium iron phosphate crystal to the surface of the crystal. Under the action of the electric field force, it enters the electrolyte, passes through the separator, and then migrates to the surface of the graphite crystal through the electrolyte. It is then embedded into a graphite lattice. At the same time, electrons flow to the aluminum foil collector of the positive electrode through the conductor and to the copper foil current collector of the negative electrode through the tab, battery pole, external circuit, negative pole, and negative tab. Then, it flows through the conductor to the graphite negative electrode to balance the charge on the negative electrode. After the lithium ions are deintercalated from the lithium iron phosphate, the lithium iron phosphate is converted into iron phosphate.

When the LFP battery is discharged, lithium ions are deintercalated from the graphite crystal, enter the electrolyte, and pass through the separator. Then, it migrates to the surface of the lithium iron phosphate crystal through the electrolyte and then is embedded into the crystal lattice of the lithium iron phosphate again through the surface. At the same time, the battery flows to the copper foil collector of the negative electrode through the conductor. It flows to the aluminum foil current collector of the battery’s positive electrode through the tab, negative battery post, external circuit, positive post, and positive tab. Then, it flows through the conductor to the lithium iron phosphate positive electrode to balance the charge of the positive electrode.
When using the left battery, pay attention to waterproofing and dustproofing, so there should be no water in the storage place, which will affect the performance and service life of the battery.

Part 2. Charging lithium phosphate batteries

It is recommended to use the CCCV charging method for charging lithium iron phosphate battery packs, that is, constant current first and then constant voltage. The constant current recommendation is 0.3C. The constant voltage recommendation is 3.65V.

Are LFP batteries and lithium-ion battery chargers the same?

The charging method of both batteries is a constant current and then a constant voltage (CCCV), but the constant voltage points are different.
The nominal voltage of a lithium iron phosphate battery is 3.2V, and the charging cut-off voltage is 3.6V.
The nominal voltage of ordinary lithium batteries is 3.6V, and the charging cut-off voltage is 4.2V.

Charging LiFePO4 batteries with solar

Solar panels cannot directly charge lithium-iron phosphate batteries. Because the voltage of solar panels is unstable, they cannot directly charge lithium-iron phosphate batteries. A voltage stabilizing circuit and a corresponding lithium iron phosphate battery charging circuit are required to charge it.

Charging lithium iron phosphate batteries with a generator

The generator cannot directly charge the LiFePO4 battery because the power generated by the generator is alternating or pulsed direct current. The LiFePO4 battery must be charged with regulated direct current.

Part 3. How to extend the life of the LiFePO4 battery?

Power batteries are composed of batteries in groups, which are realized by connecting single cells in series and parallel. Due to its characteristics, lithium-ion phosphate battery packs have high requirements for the consistency of single cells. As long as one battery in a group of batteries differs from the others, the effectiveness of the entire battery pack will be greatly reduced. Moreover, the cycle life of the LFP battery is related to the quality, specifications, frequency of use, charging and discharging methods, and other factors of the battery. Therefore, when using lithium iron batteries, pay attention to usage and maintenance to minimize unnecessary losses and extend the battery’s cycle life.

1. Avoid overcharging and discharging

Lithium-ion batteries are particularly sensitive to overcharging and discharging, so avoid charging more than 100% or discharging less than 20%. Charging when the battery power drops to about 30% is recommended. Keeping battery power between 40-80% can slow down the battery’s cycle age.

2. Control charging time

The charging time should not be too long. It is recommended to use the original charger or a brand charger that meets the standards for charging and cuts off the power in time after it is fully charged.

3. Keep the battery clean

Clean the dust and dirt on the battery surface frequently to prevent dust and debris from entering the battery and affecting battery life.

4. Avoid high and low-temperature environments

High and low-temperature environments have a certain impact on lithium-ion batteries. Temperatures that are too high or too low will shorten the battery life. You should avoid exposing the battery to high or low temperatures and keep the battery temperature between 5-35 degrees Celsius.

5. Avoid being crushed by heavy objects

The casing of lithium iron batteries is generally thin. It should be protected from being crushed or squeezed by heavy objects to prevent battery deformation or internal short circuits.

6. Regular maintenance

Regular maintenance and upkeep of the battery, such as checking the tightening of battery connectors, cleaning battery terminals, checking battery connection lines, etc., can keep the battery in good condition and extend its service life.

7. Lithium iron phosphate battery charger

Use a dedicated charger. Suppose the current and voltage of the LFP battery and the charger do not match. In that case, the battery is likely to be damaged, and the battery life will be affected. Therefore, be sure to use a regular dedicated supporting charger for charging. Do not mix new and old lithium batteries or different types of lithium battery chargers.

Part 4. Lithium ion phosphate battery pack charging ways

1. Constant voltage charging

During the charging process, the output voltage of the charging power source remains constant. As the state of charge of the lithium-ion phosphate battery pack changes, the charging current is automatically adjusted. Suppose the specified voltage constant value is appropriate. In that case, it can not only ensure the full charging of the power battery but also minimize gas evolution and water loss. This charging method only considers changes in a single state of battery voltage. It cannot effectively reflect the overall charging status of the battery. Its initial charging current is too large, which often causes damage to the power battery. Given this shortcoming, constant voltage charging is rarely used.

2. Constant current charging

During the charging process, the charging current is kept constant by adjusting the output voltage. Keeping the charging current constant, the charging rate is relatively low. The constant current charging control method is simple. However, since the acceptable current capability of the lithium battery pack gradually decreases as the charging process proceeds, in the later stages of charging, the power battery’s ability to receive electricity decreases and the charging current utilization rate is greatly reduced. The advantages of this method are simple operation, convenience, easy implementation, and easy calculation of charging capacity.

3. Constant current and constant voltage charging

This charging method is a simple combination of the two mentioned above. The first stage adopts the constant current charging method to avoid excessive charging current at the beginning of constant voltage charging. The second stage uses a constant voltage charging method to avoid overcharging caused by constant current charging. The lithium-ion phosphate battery pack is the same as any other sealed rechargeable battery. Charging must be controlled, and overcharging is not allowed. Otherwise, the battery may be easily damaged. LFP batteries generally use a charging method of constant current first and then voltage limiting.

4. Chopping charge

Charging is done using the chopper method. Under this method, the current of the constant current source remains unchanged, and the switch tube is controlled to be turned on for some time and then turned off for some time, and the cycle repeats. The advantage of this method is that when the battery is charged through an external circuit, the ion generation inside the battery requires a certain response time, and if it is continuously charged, it may reduce its capacity potential. After charging for a period of time, adding a shutdown time allows the ions generated at the two poles of the battery to diffuse, giving the battery a “digestion” time. This will greatly increase the utilization rate of the lithium-ion phosphate battery pack and improve the charging effect.

FAQs

What is the best way to charge a LiFePO4 battery?

The best way to charge a LiFePO4 battery is to use a charger specifically designed for LiFePO4 batteries, which provides the appropriate voltage and charging algorithm for optimal performance and safety.
Should I charge LiFePO4 100%?

Charging LiFePO4 batteries to around 80-90% of their capacity for regular use is generally recommended. Charging them to 100% occasionally can help balance the cells, but frequent full charges may reduce their lifespan.
Do I need a special charger for the LiFePO4 battery?

Yes, using a charger specifically designed for LiFePO4 batteries is important. LiFePO4 batteries require a different charging algorithm than other battery chemistries, and using a charger with the correct voltage and charging profile ensures safe and efficient charging.
How do I know if my LiFePO4 battery is fully charged?

By monitoring the charging voltage and current, you can determine if a LiFePO4 battery is fully charged. When the battery reaches its maximum voltage and the charging current drops to a very low level (usually below 5% of the battery’s capacity), it is an indication that the battery is fully charged.